Enantioselevtive compexation of chiral lariat crown ethers and chiral primary alkylamonum perchlorates
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KünyeAral, T., Köylü, M.Z., Kocakaya, Ş.Ö., Hoşgören, H. (2011). Enantioselevtive compexation of chiral lariat crown ethers and chiral primary alkylamonum perchlorates. Turkish Journal Chemistry 25 (2) , pp.171-179
In order to investigate the enantiomeric recognition abilities toward 2 chiral alkylammonium perchlorates (AmI, AmII) by 1 H-NMR titration method in CDCl 3, 4 chiral lariat ethers 8-11 with a (p-methoxyphenoxy) methyl flexible side arm were used. The most effective enantiomeric recognition was obtained by LCEs 9 and 11 toward AmII, by KR /KS 6.58 and KS /KR 6.63, respectively. The effect of macroring size, subunit of macroring, and side arm appeared to have strong influence on the binding ability of these alkylammonium ions.
KaynakTurkish Journal Chemistry
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