Aral, TarıkKöylü, Mehmet ZaferKocakaya, Şafak ÖzhanKarakaplan, MehmetHoşgören, Halil2021-03-292021-03-292011-02-01Aral, T., Köylü, M.Z., Kocakaya, Ş.Ö., Hoşgören, H. (2011). Enantioselevtive compexation of chiral lariat crown ethers and chiral primary alkylamonum perchlorates. Turkish Journal Chemistry 25 (2) , pp.171-1791303-61301300-0527https://dergipark.org.tr/tr/pub/tbtkchem/issue/11893/142148https://hdl.handle.net/20.500.12402/2795In order to investigate the enantiomeric recognition abilities toward 2 chiral alkylammonium perchlorates (AmI, AmII) by 1 H-NMR titration method in CDCl 3, 4 chiral lariat ethers 8-11 with a (p-methoxyphenoxy) methyl flexible side arm were used. The most effective enantiomeric recognition was obtained by LCEs 9 and 11 toward AmII, by KR /KS 6.58 and KS /KR 6.63, respectively. The effect of macroring size, subunit of macroring, and side arm appeared to have strong influence on the binding ability of these alkylammonium ions.eninfo:eu-repo/semantics/openAccessAttribution-NonCommercial-ShareAlike 3.0 United StatesChiral Lariat Crown EthersEnantioselectivityComplexation PropertiesMolecular RecognitionNMR TitrationArticle35171179Q3N/A