Imine containing C2-Symmetric chiral half sandwich h6-p-cymene-Ru(II)- phosphinite complexes: Investigation of their catalytic activityin the asymmetric transfer hydrogenation of ketones

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dc.authorid0000-0002-6612-2751en_US
dc.contributor.authorAral, Tarık
dc.contributor.authorPaşa, Salih
dc.contributor.authorKayan, Cezmi
dc.contributor.authorMeriç, Nermin
dc.contributor.authorSünkür, Murat
dc.contributor.authorAydemir, Murat
dc.contributor.authorBaysal, Akın
dc.contributor.authorDurap, Feyyaz
dc.contributor.authorSaleh, Najmuldain Abdullah
dc.date.accessioned2021-03-23T07:18:46Z
dc.date.available2021-03-23T07:18:46Z
dc.date.issued2020-01-15en_US
dc.departmentBatman Üniversitesi Fen - Edebiyat Fakültesi Kimya Bölümüen_US
dc.description.abstractNew chiral C2-symmetric bis(phosphinite) ligands containing imine group were synthesized from 1-({[(1R,2R)-2-{[(2-hydroxynaphthalen-1-yl)methylidene] amino}cyclohexyl]- imino}methyl)- naphthalen-2-ol and two equivalents of Ph2PCl, (i-Pr)2PCl or (Cy)2PCl, in high yields. Binuclear C2-symmetric half sandwich η6-p-cymene-Ru(II) complexes of the chiral phosphinite ligands were synthesized by treating of [Ru(η6-p-cymene)(μ-Cl)Cl]2 with the phosphinites in 1:1 M ratio in CH2Cl2. Their catalytic activities in asymmetric transfer hydrogenation (ATH) were investigated for the reaction of acetophenone derivatives with isopropyl alcohol. The corresponding optically active secondary alcohols were obtained in excellent levels of conversion (96–99%) and moderate enantioselectivity (up to 60% ee). Among three complexes investigated, complex 4 was the most efficient one.en_US
dc.identifier.citationSaleh, A.N., Aral, T., Paşa, S., Kayan, C., Meriç, N., Sünkür, M., Aydemir, M., Baysal, A., Durap, F. (2020). Imine containing C2-Symmetric chiral half sandwich η6-p-cymene-Ru(II)- phosphinite complexes: Investigation of their catalytic activity in the asymmetric transfer hydrogenation of ketones. Journal of Molecular Structure, 1200 (127146), pp. 1-8. https://dx.doi.org/doi.org/10.1016/j.molstruc.2019.127146en_US
dc.identifier.endpage8en_US
dc.identifier.issn0022-2860
dc.identifier.issue127146en_US
dc.identifier.scopusqualityQ2en_US
dc.identifier.startpage1en_US
dc.identifier.urihttps://dx.doi.org/doi.org/10.1016/j.molstruc.2019.127146
dc.identifier.urihttps://hdl.handle.net/20.500.12402/2762
dc.identifier.volume1200en_US
dc.identifier.wosqualityQ2en_US
dc.indekslendigikaynakWeb of Scienceen_US
dc.indekslendigikaynakScopusen_US
dc.language.isoenen_US
dc.publisherJournal of Molecular Structureen_US
dc.relation.isversionof10.1016/j.molstruc.2019.127146en_US
dc.relation.journalJournal of Molecular Structureen_US
dc.relation.publicationcategoryMakale - Ulusal Hakemli Dergi - Kurum Öğretim Elemanıen_US
dc.rightsinfo:eu-repo/semantics/embargoedAccessen_US
dc.rightsAttribution-NonCommercial-ShareAlike 3.0 United States*
dc.rights.urihttp://creativecommons.org/licenses/by-nc-sa/3.0/us/*
dc.subjectPhosphiniteen_US
dc.subjectPhosphiniteen_US
dc.subjectChiralen_US
dc.subjectChiralen_US
dc.subjectCatalysisen_US
dc.subjectCatalysisen_US
dc.subjectAsymmetric Transfer Hydrogenationen_US
dc.subjectAsymmetric Transfer Hydrogenationen_US
dc.subjectRutheniumen_US
dc.subjectRutheniumen_US
dc.titleImine containing C2-Symmetric chiral half sandwich h6-p-cymene-Ru(II)- phosphinite complexes: Investigation of their catalytic activityin the asymmetric transfer hydrogenation of ketonesen_US
dc.typeArticleen_US

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