Novel bis(aminoalcohol)oxalamide organogelators and their diglycolylamide analogs: evaluation of gelation efficiency in various organic fluids

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dc.authorid0000-0002-3774-2652en_US
dc.authorid0000-0001-5860-2133en_US
dc.authorid0000-0001-9805-9745en_US
dc.contributor.authorÇolak, Mehmet
dc.contributor.authorPirinççioğlu, Necmettin
dc.contributor.authorHoşgören, Halil
dc.contributor.authorBarış Cebe, Deniz
dc.date.accessioned2021-04-09T06:40:25Z
dc.date.available2021-04-09T06:40:25Z
dc.date.issued2017-11-10en_US
dc.departmentBatman Üniversitesi Fen - Edebiyat Fakültesi Kimya Bölümüen_US
dc.description.abstractThree modular types of bis(aminoalcohol)oxalamides (1, 4, and 7) and bis(aminoalcohol)diglycolylamide (8) gelators have been prepared by the reaction of the respective aminoalcohols with oxalyl and digycolyl methylesters as potential low-molecular-weight organogelators. The gelation properties of these amides have been evaluated in various aromatic organic solvents (xylene, toluene, isopropyl benzene, and aromatic ether type organic fluids such as anisole or α-phenylethylmethylether) as well as the long-chain aliphatic alcohols (1-hexanol, 1-octanol, 2-octanol, and aromatic 1- phenylethanol). The compounds with sec-butyl and ethyl side chains produce good gelation properties in both aromatic and other organic fluids. Furthermore, the common oxalamide linker present in the gelators was replaced by an extended diglycolylamide linker (8) and its behaviors were compared with the benzylic oxalamide analog (3). The gelator (8) gives the best results with aromatic fluid and lauric acid ethyl ester. 1 H NMR studies reveal the existence of temperaturedependent network assembly/dissolution equilibrium and produce Kgel . FTIR was employed to see the effect of hydrogen bonding in the formation of gel network. Thermodynamic parameters regarding gel-to-sol transition were collected with van’t Hoff relationships.en_US
dc.identifier.citationÇolak, M., Barış Cebe, D., Pirinççioğlu, N., Hoşgören, H. (2017). Novel bis(aminoalcohol)oxalamide organogelators and their diglycolylamide analogs: evaluation of gelation efficiency in various organic fluids. Turkish Journal of Chemistry, 41 (5), pp. 658-671. https://doi.org/10.3906/kim-1701-76en_US
dc.identifier.endpage671en_US
dc.identifier.issn1303-6130
dc.identifier.issn1300-0527
dc.identifier.issue5en_US
dc.identifier.scopusqualityQ3en_US
dc.identifier.startpage658en_US
dc.identifier.urihttps://doi.org/10.3906/kim-1701-76
dc.identifier.urihttps://journals.tubitak.gov.tr/chem/issues/kim-17-41-5/kim-41-5-5-1701-76.pdf
dc.identifier.urihttps://hdl.handle.net/20.500.12402/2822
dc.identifier.volume41en_US
dc.identifier.wosqualityN/Aen_US
dc.indekslendigikaynakWeb of Scienceen_US
dc.indekslendigikaynakScopusen_US
dc.language.isoenen_US
dc.publisherTÜBİTAKen_US
dc.relation.isversionof10.3906/kim-1701-76en_US
dc.relation.journalTurkish Journal of Chemistryen_US
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US
dc.rightsinfo:eu-repo/semantics/openAccessen_US
dc.rightsAttribution-NonCommercial-ShareAlike 3.0 United States*
dc.rights.urihttp://creativecommons.org/licenses/by-nc-sa/3.0/us/*
dc.subjectGelationen_US
dc.subjectSelf-Assemblyen_US
dc.subjectLow-Molecular-Weight Organogelsen_US
dc.subjectInfrareden_US
dc.subjectNMR Spectroscopyen_US
dc.subjectHydrogen Bondingen_US
dc.subjectChiral Amidediolsen_US
dc.titleNovel bis(aminoalcohol)oxalamide organogelators and their diglycolylamide analogs: evaluation of gelation efficiency in various organic fluidsen_US
dc.typeArticleen_US

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