Synthesis, characterization and experimental, theoretical, electrochemical, antioxidant and antibacterial study of a new Schiff base and its complexes
Yükleniyor...
Tarih
2014-09-15
Dergi Başlığı
Dergi ISSN
Cilt Başlığı
Yayıncı
Elsevier
Erişim Hakkı
info:eu-repo/semantics/embargoedAccess
Attribution-NonCommercial-ShareAlike 3.0 United States
Attribution-NonCommercial-ShareAlike 3.0 United States
Özet
A new Schiff base ligand was synthesized by reaction of salicylaldehyde with 1,6-bis(4-chloro-2-aminophenoxy)hexane. Then the Schiff base complexes were synthesized by metal salts and the Schiff base. The metal to ligand ratio of metal complexes was found to be 1:1. The Cu(II) complex is proposed to be square planar and the Co(II), Ni(II), Mn(II) and Zn(II) complexes are proposed to be tetrahedral geometry. The Ti(III) and V(III) complexes are proposed to be a capped octahedron in which a seventh ligand has been added to triangular face. The complexes are non-electrolytes as shown by their molar conductivities (ΛM). The structure of metal complexes is proposed from elemental analysis, FT-IR, UV–vis, magnetic susceptibility measurements, molar conductivity measurements, Mass Spectra and thermal gravimetric analysis. In addition antimicrobial and antioxidant studies, cyclic voltammetry of the complexes, theoretical 1H NMR and HOMO–LUMO energy calculations of the new di-functional ligand were done.
Açıklama
Anahtar Kelimeler
1,6-Bis (4-chloro-2-aminophenoxy) Hexane, Cyclic Voltammetry, Salicyaldehyde, Biological Activities, Mass Spectra, Gaussian 09 and HOMO–LUMO
Kaynak
WoS Q Değeri
Q2
Scopus Q Değeri
Q2
Cilt
130
Sayı
Künye
Baykara, H., İlhan, S., Levent, A., Seyitoğlu, M. S., Özdemir, S., Okumuş, V., Öztomsuk, A., Cornejo, M. (2014). Synthesis, characterization and experimental, theoretical, electrochemical, antioxidant and antibacterial study of a new Schiff base and its complexes. Spectrochimica Acta - Part A: Molecular and Biomolecular Spectroscopy, 130, pp. 270-279. https://doi.org/10.1016/j.saa.2014.03.094
