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Öğe Hayvansal iç yağlardan transesterifikasyon reaksiyonu ile biyodizel üretilmesi(Doğu Anadolu Bölgesi Araştırma ve Uygulama Merkezi, 2008-07-31) Altun, Şehmus; Öner, CengizHayvansal yağlar normal çevre sıcaklığında katı ve çok viskozdurlar. Yüksek viskozitelerinden dolayı dizel motorlarında kullanılmadan önce modifiye edilmeleri gerekmektedir. Hayvansal yağların dizel motorlarında kullanılabilirliliğini iyileştirmek için emülsiyon ve transesterifikasyon etkili iki yöntemdir. Bu çalışmada hayvansal iç yağlardan baz katalizörlü transesterifikasyon ile %99.7 saflıkta metil alkol ve katalizör olarak %98 saflıkta NaOH kullanılarak hayvansal iç yağı metil esteri (biyodizel) üretilmiştir. Hayvansal iç yağı, metil ester şekline dönüştükten sonra viskozitesi önemli ölçüde azalmış ve oda sıcaklığında sıvı fazında bir yakıt elde edilmiştir. Biyodizelin belirlenen yakıt özellikleri ASTM standartlarında olup, viskozitesi ve yoğunluğu dizel yakıtına yakın, ısıl değeri ise %8 daha düşük çıkmıştır.Öğe Biodiesel production from raw cottonseed oil and its characterization(Energy Education Science and Technolgy Part A, 2011-07) Altun, Şehmus; Yaşar, Fevzi; Öner, CengizIn this study, raw cottonseed oil of Turkish origin was transesterified using methyl alcohol and an alkali catalyst to obtain the cottonseed oil methyl ester. The obtained cottonseed oil methyl ester was analyzed by gas chromatography (GC) for determining the fatty acid composition. The fuel-related properties of cottonseed oil methyl ester, cold filter plugging point, cloud point, kinematic viscosity, density, cetane index, flash point, distillation, sulfur content and heating value were determined and compared with those of petroleum diesel fuel and international biodiesel standards. From gas chromatograph analysis, it was found that the cottonseed oil methyl ester has the more amount of total unsaturated FA, therefore, it showed better cold-flow properties than more saturated ones, as expected. Moreover, the fuel-related properties of cottonseed oil methyl ester were within the specified standardsÖğe The performance and emissions characteristics of a diesel engine fueled with biodiesel and diesel fuel(Kırıkkale Üniversitesi, 2010-01) Altun, Şehmus; Öner, Cengiz; Sugözü, İlkerThis paper presents the performance and emission characteristics of a diesel engine fueled with biodiesel and diesel fuel. The tests were performed in a four stroke, single cylinder, naturally aspirated, air-cooled and direct injection diesel engine at the different engine speed under full-load conditions. The results obtained with biodiesel were compared with the diesel fuel as reference fuel. The engine torque and power obtained in biodiesel were less, and the specific fuel consumption was found to be higher, which could be attributed to lower calorific value of biodiesel. CO emissions for biodiesel were lower than that of diesel fuel. However, it was observed that NOx emissions for biodiesel were higher than that of diesel fuel.Öğe Biodiesel production from raw cottonseed oil and its performance in a diesel engine(Technology, 2011) Adin, Hamit; Yaşar, Fevzi; Öner, Cengiz; Altun, ŞehmusIn this experimental work, raw cottonseed oil was converted by KOH-catalyzed transesterification reaction with methyl alcohol to the cottonseed oil methyl ester (biodiesel) and then tested in a single cylinder, four strokes and direct injection diesel engine at the constant engine speed (2000 rpm) under different engine loads. The composition and the fuel-related properties of produced biodiesel were determined by using gas chromatography (GC) and related instruments. An increase in brake specific fuel consumption (BSFC) and decrease in brake thermal efficiency (BTE) for fuel blends were observed compared with diesel fuel. Compared with diesel fuel, exhaust emissions were found to be lower in carbon monoxide, hydrocarbon, nitrogen oxides and smoke with the use of fuel blends. It was concluded that cottonseed oil methyl esterdiesel fuel blends could be substituted for the diesel fuel without any modifications in diesel engines, with better environmental characteristics of fuel blends.
