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Öğe Effects of ethanol addition to biodiesel fuels derived from cottonseed oil and its cooking waste as fuel in a generator diesel engine(Taylor & Francis, 2020-03) Karakaya, HakanExploration of energy sources such as renewable and non-edible vegetable oils has been continued during the recent two decades of 2000s. Cottonseed oil is a non-edible, abundant oil and is generally used as cooking oil. In the present study, the usability of biodiesel derived from both cottonseed oil and its cooking wastes was investigated by blending them with ULSD or ethanol in 50 percentages. B50, WB50, B50E50 and WB50E50, biodiesel and ethanol-contained fuels and ULSD were prepared for experiments. Combustion, performance, and emissions tests were conducted on a diesel engine used for power-producing electrical generator. In the combustion tests, cylinder pressure, HRR, CHR, MGT, and MFB were analyzed while MFC, BSFC, exhaust manifold temperature, and thermal efficiency were obtained in the performance tests. In the emissions tests, CO, HC, and NOx emissions were measured and compared with the results of ULSD. Combustion and performance findings of ULSD contained biodiesel blends were found more similar to those of ULSD. The duration of combustion stage can clearly be seen to be narrowed for ethanol-contained blend because of the rabid combustion characteristics of ethanol. Besides, the peak of HRR was found 10% higher for B50E50 while it was found averagely 8% for WB50E50 blends. NOx emissions were found 48% lower averagely for ethanol contained biodiesel blends that it is the most important finding of ethanol using with biodiesel. Besides, HC emissions were also found about 75% for biodiesel contained diesel fuel blends.Öğe Effect of welding parameters on microstructure and mechanical properties of AA7075/AA5182 alloys joined by TIG and MIG welding methods(SpringerLink, 2020) Çelik, Yahya Hışman; Temiz, Şemsettin; Çetkin, EdipIn this study, V and X welding grooves were opened to the forehead positions of the AA5182 and AA7075 aluminum alloy pairs and these alloy pairs were joined with tungsten inert gas (TIG) and metal inert gas (MIG) methods. Three diferent welding currents were used in joints. Gas fow rates of 12 and 17 l/min at the TIG welding and wire feed rates of 38 and 45 cm/min at MIG welding were selected. The efect of the welding grooves, welding current, gas fow rate and wire feed rate on microstructure and mechanical properties were investigated. Microstructures of welding zones were analyzed by an optical microscope and a scanning electron microscope (SEM). Vickers hardness of these zones was also measured. In addition, tensile and fatigue tests were carried out. Fracture mechanisms of failed specimens were conducted after the tensile tests were examined by using SEM. The highest hardness, tensile and fatigue strengths were obtained from the alloy pairs joined by opening X welding groove with TIG welding method. These values were 89 HV, 262.87 MPa, and 131.5 MPa, respectively. Similarly, the lowest tensile and fatigue strengths were obtained from the alloy pairs joined by opening V welding groove in the TIG welding method. These values were, respectively, 94.48 MPa and 19.1 MPa. However, the minimum hardness value was measured as 58 HV from the alloy pairs joined by opening V welding groove with MIG welding methods. In addition, it was observed on the fracture surfaces that the grain distributions and mechanisms difered depending on the welding methods, welding groove, and welding parameters.Öğe Effect of MQL flow rate on machinability of AISI 4140 steel(Taylor & Francis, 2020-06-27) Gürbüz, Hüseyin; Gönülaçar, Yunus Emre; Baday, ŞehmusMany studies were performed about the influence of minimum quantity lubrication (MQL) technique on cutting performance in the literature, but there is no paper examining the effect of different MQL flow rates and cutting parameters on machinability of AISI 4140 material as a whole. In this study, the effects of different MQL flow rates and cutting parameters on surface roughness, main cutting force and cutting tool flank wear (VB), with great importance among the machinability criteria, and forming as a result of the machining of AISI 4140, were revealed. At the end of the experiments, it was determined that rise of flow rate affected main cutting forces positively to a certain extent; yet, it exhibited no significant effect on surface roughness, but reduced VB. Also, it was observed that both main cutting force and surface roughness increased with the increase of feed, while generally decreased with the increase of cutting speed. It was seen that flank wear was positively affected by the increase in flow rate; and this decreased with the increase in flow rate. R2 values obtained as 99.8% and 99.9% for main cutting forces and surface roughness values modeled statistically with the help of quadratic equations, respectively.Öğe The flexural fatigue behavior of honeycomb sandwich composites following low velocity impacts(MDPI, 2020-01-13) Topkaya, Tolga; Solmaz, Murat YavuzThis study experimentally investigated the flexural fatigue behaviors of honeycomb sandwich composites subjected to low velocity impact damage by considering the type and thickness of the face sheet material, the cell size and the core height parameters. Carbon-fiber reinforced composite and the aluminum alloy was used as the face sheet material. First, the static strength of undamaged and damaged specimens was determined by three-point bending loads. Secondly, the fatigue behaviors of the damaged and undamaged specimens were determined. Low velocity impact damage decreased the flexural strength and fatigue lives but increased the damping ratio for all specimens. Maximum damping ratio values were observed on specimens with a aluminum face sheet.Öğe Imine containing C2-Symmetric chiral half sandwich h6-p-cymene-Ru(II)- phosphinite complexes: Investigation of their catalytic activityin the asymmetric transfer hydrogenation of ketones(Journal of Molecular Structure, 2020-01-15) Aral, Tarık; Paşa, Salih; Kayan, Cezmi; Meriç, Nermin; Sünkür, Murat; Aydemir, Murat; Baysal, Akın; Durap, Feyyaz; Saleh, Najmuldain AbdullahNew chiral C2-symmetric bis(phosphinite) ligands containing imine group were synthesized from 1-({[(1R,2R)-2-{[(2-hydroxynaphthalen-1-yl)methylidene] amino}cyclohexyl]- imino}methyl)- naphthalen-2-ol and two equivalents of Ph2PCl, (i-Pr)2PCl or (Cy)2PCl, in high yields. Binuclear C2-symmetric half sandwich η6-p-cymene-Ru(II) complexes of the chiral phosphinite ligands were synthesized by treating of [Ru(η6-p-cymene)(μ-Cl)Cl]2 with the phosphinites in 1:1 M ratio in CH2Cl2. Their catalytic activities in asymmetric transfer hydrogenation (ATH) were investigated for the reaction of acetophenone derivatives with isopropyl alcohol. The corresponding optically active secondary alcohols were obtained in excellent levels of conversion (96–99%) and moderate enantioselectivity (up to 60% ee). Among three complexes investigated, complex 4 was the most efficient one.Öğe A research on the fatigue strength of the single-lap joint joints bonded with nanoparticle-reinforced adhesive(Welding in the World, 2021-01) Adin, Hamit; Saraç, İsmail; Temiz, ŞemsettinNano-technological developments, which have made significant progress in recent years, have significant impact on the science of adhesives. Therefore, in our study, the static and fatigue strengths of single-lap joints (SLJs) incorporating nanoparticles were compared to those without nanoparticles. Steel plates were used in the adhesive joints. The results revealed that average damage load increased significantly in nanoparticle-reinforced adhesive joints. The highest damage load was obtained with 4 wt% nanoAl2O3 in epoxy adhesive. As the average damage load increased, the locus of damage changed from interfacial to the mixture of interfacial and cohesive. Also, fatigue strengths of the joints increased when the adhesive joint had nano-Al2O3 and nano-SiO2, and decreased when the adhesive joint had nano-TiO2.Öğe Effects of isopropanol-butanol-ethanol (IBE) on combustion characteristics of a RCCI engine fueled by biodiesel fuel(Journals & Books, 2021-10) Altun, Şehmus; Okcu, Mutlu; Varol, Yasin; Fırat, MüjdatThe reactivity controlled compression ignition (RCCI) strategy using fuels with different reactivity’s has attracted attention due to its high thermal efficiency as well as very low NOx and PM emissions in comparison to conventional combustion. As previous studies have shown that the type and amount of low reactivity fuel have a significant contribution to the in-cylinder reactivity, thus RCCI combustion, in this study, Iso-Propanol-Butanol-Ethanol (IBE), which has comparable characteristics to n-butanol and ethanol, is employed as low reactivity fuel (LRF) in a RCCI engine fueled by petroleum based EN590 fuel and commercial biodiesel. The IBE mixture was in volumetric ratios of 3:6:1 as in the fermentation process of butanol, that is to say; 30% Iso-Propanol, 60% Butanol and 10% Ethanol. In each experimental condition, keeping the total energy of the fuel supplied to the engine in conventional combustion mode for each cycle as constant, the premixed ratio (Rp) in case RCCI combustion was applied as 0%, 15%, 30%, 45% and 60% (the amount of LRF in energy basis) over this energy amount. The effect of premixed ratio of IBE on combustion characteristics were investigated in a single-cylinder RCCI engine under different loads with using both petroleum diesel and biodiesel as high-reactivity fuels (HRF), respectively. According to experimental results, a higher in-cylinder pressure was measured by using diesel in both conventional and RCCI mode compared to the use of biodiesel. Considering the peak in-cylinder pressure and rate of heat release, the premixed ratio (Rp) of up to 45% was found as optimum for all loads while it was up to 30%Rp for the NOx emissions. In addition, the biodiesel-fueled RCCI engine produced the lowest smoke opacity in all loads and it gradually decreased by up to 97% with the application of the RCCI strategy. Furthermore, the results showed that a simultaneous reduction in NOx and smoke opacity could be obtained under 60% load and up to 30% Rp with a marginal increase in unburned HC emissions.Öğe Empirical calculation of the optimal tilt angle for solar collectors in northern hemisphere(Taylor & Francis, 2020-03) Karakaya, Hakan; Kallioğlu, Mehmet Ali; Durmuş, Aydın; Yılmaz, AdemPanel tilt angles (0°–90°) need to be in a proper position and location to get maximum productivity from solar energy. Values used in solar energy applications are generally computed by (global, diffuse, and direct) variation on horizontal surfaces calculated using isotropic sky and a mean albedo method. Being parallel to the available literature concerning such applications, this study focuses on the optimum solar panel angle. In this study, optimum solar panel angle value by months was determined for three sample provinces (Antalya, Kayseri, and Trabzon) first and North Hemisphere then. Capacity calculation of sample provinces was performed based on monthly, seasonal, and annual angle values and horizontal situation. Monthly and annual optimum angle values for Northern Hemisphere by 1° increase for between the latitudes of 1° N and 65° N. While the panel angle is at the highest level in autumn and winter (November-December-January and February) in annual process, the lowest angle is observed in spring and summer (May-June-July-August). Several different mathematical models have been developed for the sample provinces and Northern Hemisphere. While the variable of 12 different models that were developed for provinces is the Declination (δ) coefficient, the variable of 7 different models that were developed Northern Hemisphere is the latitude (Ø). Regional values in literature with estimation results of models were analyzed based on NASA and PVGIS data color scale. There was created a possibility of comparison by aligning all the optimum solar panel angle values of related location via a scale whose values vary by 1 and 10. Moreover, all the models were verified by statistical analysis methods. R2 (determination coefficient) in 19 different estimation equations is pretty close or equal to 1. However, the best among them is Eq. 32 (0.9979) for sample provinces and Eq. (33) (1) for the Northern Hemisphere; developed models are less-than-stellar. Other statistical data of these equations are MBE (−0.0616), RMSE (1.1176), t-sat (0.1830), Bias (1). For Eq. (32); MBE (1.96), RMSE (2.75), t-sat (8.13), MPE % (3.98), MAPE (5.87), SSRE (0.27), and RSE (0.06) for Eq. (33). The statistical analyzes indicate that all regression models are applicable in Turkey and Northern Hemisphere. Developed all correlations are recommended for academic and industrial users.Öğe Empirical modeling between degree days and optimum insulation thickness for external wall(Taylor & Francis, 2020-03) Karakaya, Hakan; Kallioğlu, Mehmet Ali; Ercan, Umut; Avcı, Ali Serkan; Fidan, CihatInsulating is the most effective method that is used to save energy in buildings. Samples from cities from different climatic zones from TS 825 (Turkey) first. Optimum insulation thickness () analysis is based on two types of insulating and four different fuels (natural gas, coal, fuel oil and electric) of related cities. Cost accounts, payback period and CO2-SO2 emission calculations were performed based on these analyses. Second of all, the relationship between a number of degree day (NDD) and optimum insulation thickness () was developed by linear, quadratic and cubic correlations. Thirty different mathematical correlations based on different fuel types by using XPS and EPS insulating materials. Twenty-four of these models that were developed were generated peculiar to the fuel type; six of them were generated based on average insulation thickness. R2 values of related correlations are between 0.9989 most and 0.9952 at least as well as it is pretty close to (R ≤ 1) one value. The model among these models is the cubic mathematical model that gives the best average value. a = 0.0036, b = 5E-05, c = – 7E-09 and d = 6E-13 are the values for XPS material. Following values are for EPS material; a = 0.0028, b = 5E-13, c = – 7E-09 and d = 4E-05. R2 determination coefficient of both two equations is pretty close to 0.9989 and 1; the models obtained are less-than-stellar. Optimum insulation thickness of the area can be known based on the type of material via the number of degree day without the need for long analyses. According to the R2 values, the use of all models is recommended for academic and industrial users.Öğe Investigation of the effect of barium-based additive on smoke and NOx emissions of a diesel engine fueled with conventional and biodiesel fuels(SpringerLink, 2020-06-13) Altun, Şehmus; Arca Batı, ZülalNowadays, increasing energy demand and environmental and air pollution issues have spread the use of alternative fuels such as biodiesel in diesel engines. While the advantages of biodiesel that are comparable to petroleum-based diesel fuels and low unburned HC, carbon monoxide and smoke (soot) emissions make the use of this fuel environmentally signifcant; high NOx emissions are still a problem to be solved. The formation of decreased smoke reducing radiative heat transfer from combustion chamber in biodiesel engines and increase in formation of NOx due to rise in fame temperature are among the reasons reported for high NOx in the literature. In this study, in a diesel engine using biodiesel, soot emissions produced by petroleum diesel fuel were reduced to biodiesel level by using metallic additive (Ba), and NOx emissions were compared. When the amount of Ba in the fuel was increased, there was a signifcant decrease in the smoke emissions, but in this case, NOx emissions decreased slightly, while they were expected to increase. When NOx emissions of diesel and biodiesel were compared for the same or similar smoke emissions, it was seen that high NOx emissions were achieved with biodiesel. As a result, although Ba additive reduced smoke emissions, it was seen that its efect on NOx formation was not very clear.
