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Öğe Hayvansal iç yağlardan transesterifikasyon reaksiyonu ile biyodizel üretilmesi(Doğu Anadolu Bölgesi Araştırma ve Uygulama Merkezi, 2008-07-31) Altun, Şehmus; Öner, CengizHayvansal yağlar normal çevre sıcaklığında katı ve çok viskozdurlar. Yüksek viskozitelerinden dolayı dizel motorlarında kullanılmadan önce modifiye edilmeleri gerekmektedir. Hayvansal yağların dizel motorlarında kullanılabilirliliğini iyileştirmek için emülsiyon ve transesterifikasyon etkili iki yöntemdir. Bu çalışmada hayvansal iç yağlardan baz katalizörlü transesterifikasyon ile %99.7 saflıkta metil alkol ve katalizör olarak %98 saflıkta NaOH kullanılarak hayvansal iç yağı metil esteri (biyodizel) üretilmiştir. Hayvansal iç yağı, metil ester şekline dönüştükten sonra viskozitesi önemli ölçüde azalmış ve oda sıcaklığında sıvı fazında bir yakıt elde edilmiştir. Biyodizelin belirlenen yakıt özellikleri ASTM standartlarında olup, viskozitesi ve yoğunluğu dizel yakıtına yakın, ısıl değeri ise %8 daha düşük çıkmıştır.Öğe Determination of performance and exhaust emissions properties of B75 in a CI engine application(Journals & Books, 2011-09) Aydın, Hüseyin; İlkılıç, CumaliIn this study, performance and exhaust emissions of biodiesel in a compression ignition engine was experimentally investigated. Therefore, biodiesel has been made by transesterification from cotton seed oil and then it was mixed with diesel fuel by 25% volumetrically, called here as B75 fuel. B75 fuel was tested, as alternative fuel, in a single cylinder, four strokes, and air-cooled diesel engine. The effect of B75 and diesel fuels on the engine power, engine torque and break specific fuel consumption were clarified by the performance tests. The influences of B75 fuel on CO, HC, NOx, Smoke opacity, CO2, and O2 emissions were investigated by emission tests. The engine torque and power, for B75 fuel, were lower than that of diesel fuel in range of 2–3%. However, for the B75, specific fuel consumption was higher than that of diesel fuel by approximately 3%. CO2, CO, HC, smoke opacity and NOx emissions of B75 fuel were lower than that of diesel fuel. The experimental results showed that B75 fuel can be substituted for the diesel fuel without any modifications in diesel engines.Öğe Experimental investigation of the effects of diesel-like fuel obtained from waste lubrication oil on engine performance and exhaust emission(Journals & Books, 2010-10) Argunhan, Zeki; Yumrutaş, Recep; Arpa, OrhanIn this study, effects of diesel-like fuel (DLF) on engine performance and exhaust emission are investigated experimentally. The DLF is produced from waste engine lubrication oil purified from dust, heavy carbon soot, metal particles, gum-type materials and other impurities. A fuel production system mainly consisting of a waste oil storage tank, filters, a reactor, oil pump, a product storage tank, thermostats and control panel is designed and manufactured. The DLF is produced by using the system and applying pyrolitic distillation method. Characteristics, performance and exhaust emissions tests of the produced DLF are carried out at the end of the production. The characteristic tests such as density, viscosity, flash point, heating value, sulfur content and distillation of the DLF sample are performed utilizing test equipments presented in motor laboratory of Mechanical Engineering Department, University of Gaziantep, Turkey. Performance and exhaust emission tests for the DLF are performed using diesel test engine. It is observed from the test results that about 60 cc out of each 100 cc of the waste oil are converted into the DLF. Characteristics and distillation temperatures of the DLF are close to those values of a typical diesel fuel sample. It is observed that the produced DLF can be used in diesel engines without any problem in terms of engine performance. The DLF increases torque, brake mean effective pressure, brake thermal efficiency and decreases brake specific fuel consumption of the engine for full power of operation.Öğe Optimization of fuel production from waste vehicle tires by pyrolysis and resembling to diesel fuel by various desulfurization methods(Elsevier, 2012-12) Aydın, HüseyinIn this study, an alternative fuel for diesel engines was produced from waste automobile tires by the method of pyrolysis. In order to reduce the high sulfur content of the fuel, CaO, Ca(OH) 2, and NaOH catalysts were used. In addition, effects of variables such as temperature, the catalyst ratio and the N2 flow rate on yield were investigated. The highest product yield was obtained with temperature of 500 °C and 200 cm 3/min N 2 flow rate. When compared with the products obtained from initial pyrolysis, the sulfur content of the product was found to be 34.25% lower with the utilization of 5% Ca(OH) 2 in the reaction. In order to make the sulfur content of the product closer diesel fuel, the acetic acidH 2O 2, formic acidH 2O 2 and H 2SO 2 were used in different proportions. Although, the other acids were also very effective, the use of 10% H 2SO 4 reduced sulfur content of the product by 75.27%. Thus, with 5% Ca(OH) 2 and then with addition of 10% H 2SO 4, the sulfur content of the product was reduced by 83.75%. The properties of diesel fuel (DF), liquid fuel derived from waste vehicle tires (TF), low sulfur tire fuel (LSTF) and fuel mixtures of LSTFDF were analyzed. It was found that, the density and sulfur content of LSTF fuel were slightly higher than that of diesel fuel, but other features and distillation curves were very close to diesel fuel.
