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Öğe N-type InP Schottky diodes with organic thin layer: Electrical and interfacial properties(Journal of Vacuum Science & Technology B, 2010-03) Güllü, Ömer; Turut, AbdulmecitThe rectifying junction characteristics of methyl red (MR) organic film on n-type InP substrate have been studied. It has been observed that MR-based structure shows an excellent rectifying behavior and that the MR film increases the effective barrier height by influencing the space charge region of the n-type InP. The barrier height and ideality factor values for this structure have been obtained as 0.75 eV and 1.93 from the forward bias current-voltage characteristics, respectively. By using capacitance-voltage characteristics at 1 MHz, the barrier height and the carrier concentration values have been calculated as 0.93 eV and 5.13×1015 cm−3, respectively. The energy distributions of the interface states and their relaxation times have been determined from the forward bias capacitance-frequency and conductance-frequency characteristics. Moreover, it was seen that both the interface-state density and the relaxation time of the interface states decreased with bias voltage from experimental results.Öğe Biodiesel production from inedible animal tallow and an experimental investigation of its use as alternative fuel in a direct injection diesel engine(Elsevier, 2009-02-15) Altun, Şehmus; Öner, CengizIn this study, a substitute fuel for diesel engines was produced from inedible animal tallow and its usability was investigated as pure biodiesel and its blends with petroleum diesel fuel in a diesel engine. Tallow methyl ester as biodiesel fuel was prepared by base-catalyzed transesterification of the fat with methanol in the presence of NaOH as catalyst. Fuel properties of methyl ester, diesel fuel and blends of them (5%, 20% and 50% by volume) were determined. Viscosity and density of fatty acid methyl ester have been found to meet ASTM D6751 and EN 14214 specifications. Viscosity and density of tallow methyl esters are found to be very close to that of diesel. The calorific value of biodiesel is found to be slightly lower than that of diesel. An experimental study was carried out in order to investigate of its usability as alternative fuel of tallow methyl ester in a direct injection diesel engine. It was observed that the addition of biodiesel to the diesel fuel decreases the effective efficiency of engine and increases the specific fuel consumption. This is due to the lower heating value of biodiesel compared to diesel fuel. However, the effective engine power was comparable by biodiesel compared with diesel fuel. Emissions of carbon monoxide (CO), oxides of nitrogen (NOx), sulphur dioxide (SO2) and smoke opacity were reduced around 15%, 38.5%, 72.7% and 56.8%, respectively, in case of tallow methyl esters (B100) compared to diesel fuel. Besides, the lowest CO, NOx emissions and the highest exhaust temperature were obtained for B20 among all other fuels. The reductions in exhaust emissions made tallow methyl esters and its blends, especially B20 a suitable alternative fuel for diesel and thus could help in controlling air pollution. Based on this study, animal tallow methyl esters and its blends with petroleum diesel fuel can be used a substitute for diesel in direct injection diesel engines without any engine modification.Öğe The effect of Plantago major Linnaeus on serum total sialic acid, lipid-bound sialic acid, some trace elements and minerals after administration of 7,12-dimethylbenz(a)anthracene in rats(SAGE, 2012-04) Oto, Gökhan; Ekin, Suat; Özdemir, Hülya; Levent, Abdulkadir; Berber, İsmetThe present study was designed to evaluate the effect of Plantago major Linnaeus (PM) extract on serum total sialic acid (TSA), lipid-bound sialic acid (LSA), some trace elements (copper (Cu), zinc (Zn) and iron) and mineral levels (magnesium, calcium and sodium) in Wistar albino rat administrated 7,12-dimethylbenz(a)anthracene (DMBA). Rats were divided into three equal groups (n = 6). Group I comprised the control group, group II was treated with DMBA (100 mg/kg, single dose) and group III was treated with DMBA (100 mg/kg single dose) and aqueous extract of PM 100 mg/kg/day for 60 days. After 60 days, statistical analyses showed that TSA and LSA levels in DMBA and DMBA + PM groups were significantly higher compared to the control group (TSA: p < 0.01, p < 0.05; LSA: p < 0.05, p < 0.05, respectively). Serum Zn levels were decreased in subjects treated with DMBA (p < 0.01) and DMBA + PM (p < 0.05) compared to the control group values. Serum Cu levels were increased in DMBA group and PM-treated group compared to the control group values. The results of this investigation showed that the levels of TSA and LSA changed significantly, which are sensitive markers for detecting the toxic effects of DMBA. On the other hand, observed decline in Zn levels in rats from DMBA + PM group might be due to decreased generation of free radicals and oxidative stress. Results from this study suggest that PM may be partially effective in preventing carcinogenesis initiated by environmental carcinogen DMBA.Öğe The comparison of engine performance and exhaust emission characteristics of sesame oil-diesel fuel mixture with diesel fuel in a direct injection diesel engine(Elsevier, 2008-01-09) Altun, Şehmus; Bulut, Hüsamettin; Öner, CengizThe use of vegetable oils as a fuel in diesel engines causes some problems due to their high viscosity compared with conventional diesel fuel. Various techniques and methods are used to solve the problems resulting from high viscosity. One of these techniques is fuel blending. In this study, a blend of 50% sesame oil and 50% diesel fuel was used as an alternative fuel in a direct injection diesel engine. Engine performance and exhaust emissions were investigated and compared with the ordinary diesel fuel in a diesel engine. The experimental results show that the engine power and torque of the mixture of sesame oil-diesel fuel are close to the values obtained from diesel fuel and the amounts of exhaust emissions are lower than those of diesel fuel. Hence, it is seen that blend of sesame oil and diesel fuel can be used as an alternative fuel successfully in a diesel engine without any modification and also it is an environmental friendly fuel in terms of emission parameters.Öğe Performance and exhaust emissions of a DI diesel engine fueled with waste cooking oil and inedible animal tallow methyl esters(TÜBİTAK, 2011) Altun, ŞehmusThe performance and exhaust emissions of a direct injection diesel engine were experimentally investigated using 2 biodiesel fuels with promising economic perspective, one obtained from inedible animal tallow and the other from waste cooking oils. Inedible animal tallow, which is obtained from a mixture of slaughtered cattle and sheep fats collected from a local slaughterhouse during meat preparation process, was transesterified using methyl alcohol and an alkaline catalyst to produce the inedible animal tallow methyl ester. Biodiesel from waste cooking oil was produced from waste cooking oils and methyl alcohol via a transesterification reaction, and provided by a commercial biodiesel producer. In order to investigate the performance and exhaust emissions, the experiments were conducted at different engine speeds under the full load condition of the engine. The experimental results showed, compared with diesel fuel, that the biodiesel fuels resulted in a reduction in brake torque and in an increase in brake specific fuel consumption. Although both biodiesels caused reductions in carbon monoxide (CO), the NOx emissions were higher for waste cooking oil biodiesel and lower for inedible animal tallow biodiesel as compared to diesel fuel.Öğe Laws doku enerji ölçümü tabanli k-NN siniflandirici modeli ile iris tanima sistemi(IEEE, 20013-06-13) Acar, Emrullah; Özerdem, Mehmet SiraçBiyometrik tanıma teknolojisi genellikle çok pahallı ve son derece önemli güvenlik uygulamaları ile ilişkili olmuştur.İris tanıma sistemi, etkili biyometrik tanımasistemlerinden biridir. Bu çalışmada, farklı insanlardan elde edilen gözimgelerininiçerdiği irisdokuözelliklerinegörekişilerin tanınmasıamaçlanmıştır. İmgeler CASIAiris veritabanındanelde edilmiştir. İmge dokusuna duyarlı yeni yöntemlerdenbiri olanLawsDoku Enerji Ölçümü (Laws TEM) kullanılarak, iris dokusunun belirli yerelalanlarındanöznitelik vektörleri elde edilmiştir. kEn Yakın Komşu (k-NN) sınıflandırıcıparametrelerinden komşu sayısı(k) farklı değerlerde alınarak, elde edilen öznitelik vektörleri k-NN sınıflandırıcısı ile ayrıştırılmıştır. Farklı komşu sayılarına göre sisteminperformans değerlerikarşılaştırılmıştır. Sonuç olarak en yüksek ortalama performans,k-NNsınıflandırıcısınınk=1ve 2komşularıyapısında % 80.74olarak gözlemlenmiştir.Öğe Asymmetric organocatalytic efficiency of synthesized chiral β-amino alcohols in ring-opening of glycidol with phenols(Springer Nature, 2012-04-11) Aral, Tarık; Karakaplan, Mehmet; Hoşgören, HalilA series of novel chiral β-amino alcohols 3-5 and 7-10 were synthesized by regioselective ring opening of epoxides and chiral amines with a straightforward method in high yields (up to 99 %). Kinetic resolution of racemic glycidol with phenols was achieved by using chiral amino alcohols as organocatalysts. Amino alcohols 5, 8 and 10 exhibited the highest enantioselectivities with p-cresol, phenol, and p-methoxyphenol by 63, 65, 58 % ee, respectively. The moderate enantioselectivities were observed with catalyst 9b towards all the nucleophiles (34-48 % ee). The ee values of the desired 3-aryloxy-1, 2-diols were determined by HPLC. This study presents an attractive tool for the synthesis of β-blockers and structurally complex molecules.Öğe Performance and emission evaluation of a CI engine fueled with preheated raw rapeseed oil (RRO)–diesel blends(Journals & Books, 2010-03) Aydın, Hüseyin; Hanbey, HazarMany studies are still being carried out to find out surplus information about how vegetable based oils can efficiently be used in compression ignition engines. Raw rapeseed oil (RRO) was used as blended with diesel fuel (DF) by 50% oil–50% diesel fuel in volume (O50) also as blended with diesel fuel by 20% oil–80% diesel fuel in volume (O20). The test fuels were used in a single cylinder, four stroke, naturally aspirated, direct injection compression ignition engine. The effects of fuel preheating to 100 °C on the engine performance and emission characteristics of a CI engine fueled with rapeseed oil diesel blends were clarified. Results showed that preheating of RRO was lowered RRO’s viscosity and provided smooth fuel flow Heating is necessary for smooth flow and to avoid fuel filter clogging. It can be achieved by heating RRO to 100 °C. It can also be concluded that preheating of the fuel have some positive effects on engine performance and emissions when operating with vegetable oil.Öğe Dimension and insulation thickness optimization of circular flat plate solar collectors(Energy Education Science and Technology, 2011) Argunhan, ZekiIn this study, expressions for optimum radius of a circular flat plate solar collector and the optimum insulation thickness distribution are derived by using the concept of solar gain, which maximizes the life-cycle savings. For the specified condition the optimum radius has been found as 2.14 m and the optimum insulation thickness distribution on back of collectors has been formulized. The insulation material thickness distribution has been determined by performing a detailed dimensional analysis; therefore heat loss is minimized, and results are presented in graphics.Öğe Plantago major protective effects on antioxidant status after administration of 7,12-dimethylbenz(a)anthracene in rats(Asian Pacific Organization for Cancer Prevention, 2011) Oto, Gökhan; Ekin, Suat; Özdemir, Hülya; Demir, Halit; Yaşar, Semih; Levent, Abdulkadir; Berber, İsmet; Kaki, BarışAim: The present study was designed to evaluate effects of Plantago major extract on oxidative status in Wistar albino rats administrated 7,12-dimethylbenz(a)anthracene (DMBA). Methods: Rats were divided into three equal groups of 6 animals each: Group 1 controls, group 2 treated with DMBA (100 mg/kg, single dose) and group 3 receiving the DMBA and the aqueous extract at 100 mg/kg/d for 60 days. Results: Significant decrease in catalase (P<0.05), carbonic anhydrase (p≤0.01), reduced glutathione (GSH) (P<0.01) and total protein (P<0.01) values was observed in the DMBA group compared with the healthy controls and DMBA + Plantago major groups. Conclusion: The results suggest preventive effects of Plantago major on DMBA induced oxidative damage in Wistar albino rats that might be due to decreased free radical generation.
