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Öğe Hardness and wear behaviours of al matrix composites and hybrid composites reinforced with B 4 C and SiC(Springer Nature, 2019-01-15) Çelik, Yahya Hışman; Kılıçkap, ErolThe conversion into the desired shape of the metal powders using Powder Metallurgy (PM) method enables economically mass productions. This case allows producing parts with complex and high dimensional accuracy with no machining. In this study the composites and hybrid composites with Al matrix were produced using PM method with different ratios B4C and SiC. Microhardness and wear experiments of the produced composites were investigated. Wear experiments were performed at a constant speed of 0.5 m/s, application loads of 5, 10 and 15 N and sliding distances of 250, 500, and 750 m. Then, SEM images of composites and hybrid composites were captured. The increase of the reinforcement ratio in the composites contributed to the increase of the hardness. The highest hardness value was computed as 58.7 HV from 16% B4C reinforced composite. In addition, the increase in the reinforcement ratio contributed to the increase of the wear resistance. The increase in the load and sliding distance also increased the wear. The minimum weight loss was calculated as 18 mg from 5 N load, 250 m sliding distance and 16% SiC reinforced composite.Öğe New voltammetric strategy for determination and electrochemical behaviors of metformin by pencil graphite electrode in the NaOH(Indian Chemical Society, 2020) Altunkaynak, Yalçın; Yavuz, Ömer; Levent, AbdulkadirMetformin(MET), an oral antidiabetic drug commonly used in the treatment of diabetes, is a drug that increases insulin sensitivity in the biguanide group [1]. MET shows its pharmacological effect by lowering the glucose level in the blood. In the literature research, there are studies using electrochemical techniques for the analysis of MET in biological fluid and drug forms[1-6]. In this study, the electrochemical properties of MET, one of the drugs used in the treatment of diabetes, were performed using a pencil graphite electrode in NaOH (0.1 M) solution. This compound was recorded with an irreversible and diffusion controlled adsorption oxidation peak at approximately +1.28 V by cyclic voltammetry. With square wave stripping voltammetry, it was observed that the peak current signals of MET in the concentration range of 2.76-24.8 µM in 0.1M NaOH solution increased linearly. At a concentration of 2.76 µM (n = 9), the limit of detection and relative standard deviation were calculated as 9.03 nM (1.495 ngmL-1 ) and 3.25 %, respectively. This method has been successfully applied for MET analysis in pharmaceutical preparations and urine samples without any separation.Öğe The characteristic diode parameters in Ti/p-InP contacts prepared by DC sputtering and evaporation processes over a wide measurement temperature(World Scientific, 2017-06) Ejderha, Kadir; Asubay, Sezai; Yıldırım, Nezir; Güllü, Ömer; Türüt, Abdülmecit; Abay, BahattinThe titanium/p-indium phosphide (Ti/p-InP) Schottky diodes (SDs) have been prepared by thermal evaporation and DC magnetron sputtering deposition. Then, their current-voltage (I-V) characteristics have been measured in the sample temperature range of 100-400K with steps of 20K. The characteristic parameters of both Ti/p-InP SDs have been compared with each other. The barrier height (BH) values of 0.824 and 0.847 at 300K have been obtained for the sputtered and the evaporated SDs, respectively. This low BH value for the sputtered SD has been attributed to some defects introduced by the sputtered deposition technique over a limited depth in to the p-type substrate. The BH of the evaporated and sputtered diodes has decreased with the standard deviations of 58 and 64mV obeying to double-Gaussian distribution (GD) in 220-400K range, respectively, and it has seen a more sharper reduction for the BHs with the standard deviations of 93 and 106 mV in 100-220K range. The Richardson constant values of 89.72 and 53.24A(Kcm)-2 (in 220-400K range) for the evaporated and sputtered samples, respectively, were calculated from the modified ln(I0/T2)-q2σs2/2k2T2 vs (kT)-1 curves by GD of the BHs. The value 53.24A(Kcm)-2 for the sputtered sample in high temperatures range is almost the same as the known Richardson constant value of 60A(Kcm)-2 for p-type InP.Öğe Analysis of interface states of Al/DNA/p-Si MIS photovoltaic structures with DNA biomolecules using the conductance technique(Taylor & Francis, 2017-03-29) Güllü, ÖmerIn this study, we report on the calculation of interface charge distribution of metal–interlayer–semiconductor (MIS) photovoltaic diodes containing DNA biomolecules and Si semiconductor based on the conductance technique. DNA biofilms were deposited at room temperature using a simple cast method on p-type Si. Interface parameters of the Al/DNA/p-Si structures were investigated by using capacitance–voltage (C–V) and conductance–voltage (G–V) measurements as a function of frequency. The distributions of interfacial charge states and the trap relaxation times were reported. Also, photoelectric and photocapacitance properties of the diode were measured at room temperature.Öğe Prediction of pressure and temperature changes in the salt caverns of Tuz Golu underground natural gas storage site while withdrawing or injecting natural gas by numerical simulations(Springer Nature, 2019-03-13) Merey, ŞükrüTuz Golu (Salt Lake) Underground Gas Storage (UGS) Project in Turkey is being implemented. In some of salt caverns, natural gas is currently stored. While analyzing the data of Tuz Golu UGS project, it was observed that this location is appropriate for safe underground natural gas storage due to its rock salt with high purity and very low permeability. In this study, many numerical simulations for a salt cavern in Tuz Golu UGS project at different gas withdrawal and injection rates were conducted by using TOUGH+RealGasBrine simulator. According to the results of these numerical simulations, the temperature inside salt cavern reduced below 0 degrees C from 53 degrees C within 20days at a rate of gas withdrawal of 3.33 million standard m(3)/day due to Joule-Thomson effect. The temperature inside salt cavern reduced below 0 degrees C within 25days, 40days, and 60days at a rate of gas withdrawal of 2.5, 1.67, and 0.833 million standard m(3), respectively. In order to avoid fracture around the walls of salt cavern, the temperature change inside salt cavern should not be higher than 30 degrees C. In the numerical simulations, there is no gas seepages from the salt cavern to other neighbor salt caverns, which are 600m away owing to very low permeability of salt rock in the study area. The implication of this study is that gas withdrawal and gas injection profiles are quite important to keep the temperature inside salt caverns at an optimum range for safe natural gas storage.Öğe Separation, optimization, and quantification of cytokinins by a recently developed amide-embedded stationary phase(Taylor & Francis, 2017-07-06) Aral, Hayriye; Haşimi, Duygu; Aral, Tarık; Levent, Abdulkadir; Ziyadanoğulları, BerrinIn this study, some plant growth regulators known as cytokinins [kinetin (K), zeatin (Z), thidiazuron (TDZ), benzylaminopurine (BAP), and dimethylallylaminopurine (AAP)] were separated by HPLC using an amide-embedded mixed-mode stationary phase which was synthesized by Aral et al. in recent years. The effect of mobile phase content, mobile phase pH, buffer concentration, and temperature on separation process was studied. In addition, a quantitative determination of cytokinins from Salvia limbata extract was studied, and some validation parameters such as limit of detection (LOD), limit of quantification (LOQ), and relative standard deviation (RSD) were calculated as a range of 0.03–0.1, 0.1–0.26 mg/L, and 0.03–0.08, respectively.Öğe Investigation of the effect of different variables on strength of adhesive joints(WILEY, 2014-10-01) Adin, Hamit; Deniz, Mehmet EminIn this article, the tensile strength of different adhesive bonded joints under a tensile load was analyzed numerically. The effects of certain parameters, including the bonding length and bonding ratio, were investigated. For this reason, the epoxy adhesive was used. Joints were prepared with aluminum materials. The stress analyses were employed using the Finite Element Method (FEM). ANSYS (v.14.0.1) FEM tool was utilized to investigate the stress distribution characteristics of aluminum lap joint under tensile loading. Numerical results were found to be quite reasonable. The numerical results show that the influences of variations are very notable when the equivalent stresses are between 18 MPa and 20 MPa. © 2014 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.Öğe Beyond tourism and taxes: The ecomuseum and social development in the Ak-Chin tribal community(Taylor & Francis, 2019-03-26) Doğan, Mustafa; Timothy, Dallen J.Ecomuseums, which reflect the heritage of places, can be an important model for advancing the relationship between tourism, heritage, and local development. This paper examines the relationship between an ecomuseum and development in the context of the Ak-Chin Him-Dak Ecomuseum in Arizona, the only officially designated ecomuseum in the United States. Based on a case study approach, the study indicates that the Ak-Chin Him-Dak Ecomuseum has several features that differentiate it from many other ecomuseums around the world. Unlike some other examples, the Ak-Chin Him-Dak Ecomuseum’s primary aim is to ensure cultural revitalization and social development based on the native tribe’s unique needs. The relationship with tourism is limited, and utilizing the ecomuseum as an economic driver was not a consideration. In this case, the ecomuseum was conceived as an educational tool to aid residents in rediscovering their unique heritage, preserving elements of the past that are on the verge of disappearing, and advancing the social wellbeing of the community.Öğe New inner product quasilinear spaces on interval numbers(Hindawi, 2016) Bozkurt, Hacer; Yılmaz, YılmazPrimarily we examine the new example of quasilinear spaces, namely, "IRn interval space." We obtain some new theorems and results related to this new quasilinear space. After giving some new notions of quasilinear dependence-independence and basis on quasilinear functional analysis, we obtain some results on IRn interval space related to these concepts. Secondly, we present Is,Ic0,Il∞, and Il2 quasilinear spaces and we research some algebraic properties of these spaces. We obtain some new results and provide an important contribution to the improvement of quasilinear functional analysis.Öğe Determination of trace metal and mineral levels in the tobacco and cigarette samples using by FASS(Chemical Society of Pakistan, 2013-04) Levent, Abdulkadir; Yardım, Yavuz; Demir, CengizCigarettes and tobacco products are consumed in large amounts by human beings in the world. Also, tobacco is one of the most important agricultural products in Turkey. The accumulation of heavy metals in tobacco leaves in accordance with a possible risk of transferring them to people by smoke is well known. This study was carried out to estimate trace metal and mineral levels in tobacco and cigarettes from Eastern and South-eastern Anatolia, Turkey. The analysis was done by flame atomic absorption spectrometry using dry ashing or wet digestion. Results obtained are in agreement with data reported in the literature.
